762 | 0 | 10 |
下载次数 | 被引频次 | 阅读次数 |
磷石膏是湿法磷酸生产的副产物,由于其杂质含量高、成分复杂,长期以来难以处理,多以堆存方式处理,对环境产生重大危害。介绍磷石膏的产生过程、主要杂质赋存形式及危害。重点阐述磷石膏无害化研究现状以及资源化利用现状,无害化研究主要包括物理法、化学法以及热分解法三大类,经无害化处理后的磷石膏主要可应用于建材、化工、农业三大领域。
Abstract:Phosphogypsum is a by-product of wet-process phosphoric acid,which is difficult to deal with for a long time due to excessive impurities and complex composition,and it is mainly stockpiled,which causes major harm to the environment. The production process,impurity types and storage status of phosphogypsum are introduced. The harmless research mainly includes three categories:physical method,chemical method and thermal decomposition method,and the phosphogypsum after harmless treatment can be mainly used in the three fields of building materials,chemical industry and agriculture.
[1]崔荣政,白海丹,高永峰,等.磷石膏综合利用现状及“十四五”发展趋势[J].无机盐工业,2022,54(4):1-4.CUI R Z,BAI H D,GAO Y F,et al. Current situation of comprehensive utilization of phosphogypsum and its development trend of 14th Five-Year Plan[J]. Inorganic Chemicals Industry,2022,54(4):1-4.
[2]李光明,李霞,贾磊,等.国内外磷石膏处理和处置概况[J].无机盐工业,2012,44(10):11-13.LI G M,LI X,JIA L,et al. General situation of treatment and disposal of phosphogypsum[J]. Inorganic Chemicals Industry,2012,44(10):11-13.
[3]刘梅,高利坤,何海洋,等.磷石膏杂质脱除、稀土回收及资源化利用研究进展[J].化工矿物与加工,2023,52(10):24-31.LIU M,GAO L K,HE H Y,et al. Research progress in removal of impurities and recovery of rare earth from phosphogypsum and its resource utilization[J]. Industrial Minerals&Processing,2023,52(10):24-31.
[4]杨皓奇,武发德,朱干宇,等.天然陈化对磷石膏理化性质的影响及作用机理研究[J].新型建筑材料,2023,50(5):99-105.YANG H Q, WU F D, ZHU G Y, et al. The effect and mechanism of natural aging procedure on the physicochemical properties of phosphogypsum[J]. New Building Materials,2023,50(5):99-105.
[5]杜明霞,王进明,董发勤,等.磷石膏资源化利用研究进展[J].矿产保护与利用,2020,40(3):121-126.DU M X,WANG J M,DONG F Q,et al. Research Progress on Resource Utilization of Phosphogypsum[J]. Conservation and Utilization of Mineral Resources,2020,40(3):121-126.
[6]李恒,张晖,钟晋,等.无水Ⅱ型石膏活性激发及应用研究现状[J].化工矿物与加工,2023,52(5):1-8.LI H,ZHANG H,ZHONG J,et al. Research status on activation and application ofⅡ-anhydrite gypsum[J]. Industrial Minerals&Processing,2023,52(5):1-8.
[7]郭志翔,王琴,张秋臣,等.氟化物对石膏基胶凝材料结构和性能的影响[J].硅酸盐通报,2023,42(9):3248-3257.GUO Z X,WANG Q,ZHANG Q C,et al. Effect of Fluoride on Structure and Properties of Gypsum-Based Cementitious Materials[J]. Bulletin of the Chinese Ceramic Society,2023,42(9):3248-3257.
[8] XIANG J C,QIU J P,SONG Y Y,et al. Synergistic removal of phosphorus and fluorine impurities in phosphogypsum by enzyme-induced modified microbially induced carbonate precipitation method[J]. Journal of Environmental Management,2022,324:116300.
[9] MEHROTRA D K. Effect of deficiency of essential elements and toxicity of metals on human health[J]. Sustainable Solutions for Elemental Deficiency and Excess in Crop Plants,2020:69-82.
[10] LEI Y,ZHU Q,CHEN H,et al. Development and Application of Phosphogypsum in Plasterboard[J]. Mater Sci,2019(9):69-78.
[11] OUIKHALFAN M,LAKBITA O,DELHALI A,et al. Toward net-zero emission fertilizers industry:greenhouse gas emission analyses and decarbonization solutions[J]. Energy&Fuels,2022,36(8):4198-4223.
[12]宋青松.化工高盐度废水治理技术分析[J].资源节约与环保,2022(9):97-100.SONG Q S. Analysis of chemical high salinity wastewater treatment technology[J]. Resources Economization&Environmental Protection,2022(9):97-100.
[13]张茹,李艳军,刘杰,等.磷石膏的综合利用及有害元素处理方法[J].矿产保护与利用,2015(2):50-54.ZHANG R,LI Y J,LIU J,et al. Utilization of Phosphogypsum and Treatment of the Impure Elements[J]. Conservation and Utilization of Mineral Resources,2015(2):50-54.
[14] HASSOUNE H,LACHEHAB A,HAJJAJI K E,et al. Dynamic of Heavy Metals and Environmental Impact of Waste Phosphogypsum[J]. Fate and Transport of Subsurface Pollutants,2020,24:57-77.
[15] FU Z S,XI S H. The effects of heavy metals on human metabolism[J]. Toxicology Mechanisms and Methods,2020,30(3):167-176.
[16] LV X F,XIANG L. The generation process,impurity removal and high-value utilization of phosphogypsum material[J].Nanomaterials,2022,12(17):3021.
[17] WANG J,DONG F,WANG Z,et al. A novel method for purification of phosphogypsum[J]. Physicochemical Problems of Mineral Processing,2020,56(5):975-983.
[18]曾明,阮燕,陈晶,等.磷石膏不同预处理方法的效果比较[J].建材世界,2011,32(2):18-21.ZENG M,RUAN Y,CHEN J,et al. Effects Comparison of Different Pretreatment Methods to Phosphogypsum[J]. The World of Building Materials,2011,32(2):18-21.
[19]田家新,彭伟军,苗毅恒,等.磷石膏漂白—煅烧增白工艺研究[J].矿产保护与利用,2021,41(3):76-80.TIAN J X,PENG W J,MIAO Y H,et al. Study on Whitening of Phosphogypsum via Bleaching and Calcination[J]. Conservation and Utilization of Mineral Resources,2021,41(3):76-80.
[20]王进明,董发勤,王肇嘉,等.磷石膏浮选增白净化新工艺研究[J].非金属矿,2019,42(5):1-5.WANG J M,DONG F Q,WANG Z J,et al. Study on New Technology of Phosphogypsum Whitening and Purification by Flotation[J]. Non-Metallic Mines,2019,42(5):1-5.
[21] MURALI G, AZAB M. Recent research in utilization of phosphogypsum as building materials:review[J]. Journal of Materials Research and Technology,2023,25:960-987.
[22] XU P J,LI H,CHEN Y X. Experimental study on optimization of phosphogypsum suspension decomposition conditions under double catalysis[J]. Materials(Basel),2021,14(5):1120.
[23]付全军,罗蜀峰,马先林,等.浸取中和法脱除磷石膏中杂质的研究[J].无机盐工业,2015,47(7):44-47.FU Q J,LUO S F,MA X L,et al. Impurities removal from phosphogypsum by leaching neutralization method[J]. Inorganic Chemicals Industry,2015,47(7):44-47.
[24]刘卫海.铵法处理磷石膏制硫酸钾的研究[J].湖南化工,1999(4):26-28.LIU W H. A Study on Preparation of Potassium Sulfate from Phosphogypsum by Ammonium Bicarbonate Process[J]. Hunan Chemical Industry,1999(4):26-28.
[25]杨勇,赵婧男.高效化学沉淀法处理磷石膏堆场渗滤液工程实例[J].工业安全与环保,2023,49(1):93-96.YANG Y,ZHAO J N. Engineering example of high efficient chemical precipitation method for treating leachate of phosphogypsum yard[J]. Industrial Safety and Environmental Protection,2023,49(1):93-96.
[26] ZHANG W Y,ZHAO L Y,XUE M F,et al. Efficient precipitation of soluble phosphorus impurities in the recycling of phosphogypsum to produce hemihydrate gypsum[J]. Journal of Cleaner Production,2023,396:136455.
[27] YU M H,ZHU Z Y,LI H P,et al. Advanced preparation and processing techniques for high energy fuel AlH3[J]. Chemical Engineering Journal,2021,421(P1):129753.
[28] BANKOVI?-ILI?I B,MILADINOVI?M R,STAMENKOVI?O S,et al. Application of nano CaO-based catalysts in biodiesel synthesis[J]. Renewable and Sustainable Energy Reviews,2017,72:746-760.
[29]吴泳霖,张伟,奠波,等.磷石膏热分解研究现状[J].硅酸盐通报,2022,41(9):3129-3137.WU Y L,ZHANG W,DIAN B,et al. Research Status of Phosphogypsum Pyrolysis[J]. Bulletin of the Chinese Ceramic Society,2022,41(9):3129-3137.
[30] FENG H,XIE R S. Phosphogypsum pyrolysis with mineralization agent under weak reducing atmosphere[J]. IOP Conference Series:Earth and Environmental Science,2019,295(5):052030.
[31] ZHENG D L,MA L P,WANG R M,et al. Research on thermal decomposing properties of phosphogypsum with Fe addition under multiatmosphere control[J]. Thermochimica Acta,2018,661:59-66.
[32] YANG J,ZHU B,MA L P,et al. Investigation of Al2O3and Fe2O3transmission and transformation during the decomposition of phosphogypsum[J]. Chinese Journal of Chemical Engineering,2019,27(5):1125-1131.
[33] ZHENG S C,CHENG F X,WANG Z J. Production of SO2and lime from phosphogypsum reduced with lignite in a nitrogen atmosphere[J]. Advanced Materials Research,2013,803:94-98.
[34] NING P, ZHENG S C, MA L P, et al. Kinetics and thermodynamics studies on the decompositions of phosphogypsum in different atmospheres[J]. Advanced Materials Research,2010(160-162):842-848.
[35]李兵,包炜军,郑义文,等.磷石膏净化预处理技术[J].磷肥与复肥,2018,33(3):28-31.LI B,BAO W J,ZHENG Y W,et al. Pretreatment technology for phosphogypsum purification[J]. Phosphate&Compound Fertilizer,2018,33(3):28-31.
[36]孔霞,罗康碧,李沪萍,等.硫酸酸浸法除磷石膏中杂质氟的研究[J].化学工程,2012,40(8):65-68.KONG X,LUO K B,LI H P,et al. Removing impurity fluorine from phosphogypsum by sulfuric acid leaching method[J].Chemical Engineering,2012,40(8):65-68.
[37]谭明洋,相利学,李国龙.磷石膏净化处理及其对水泥性能的影响[J].水泥工程,2016,20(2):17-18.TAN M Y,XIANG L X,LI G L. Phosphogypsum purification treatment and its effect on cement properties[J]. Cement Engineering,2016,20(2):17-18.
[38]周武,李杨,冯伟光,等.磷石膏的综合利用及其在建筑材料领域的应用研究进展[J].硅酸盐通报,2024,43(2):534-542.ZHOU W,LI Y,FENG W G,et al. Research Progress on Comprehensive Utilization of Phosphogypsum and Its Application in the Field of Building Materials[J]. Bulletin of the Chinese Ceramic Society,2024,43(2):534-542.
[39]邓华,侯硕旻,李中军,等.磷石膏综合利用现状及展望[J].无机盐工业,2024,56(1):1-8.DENG H,HOU S M,LI Z J,et al. Current situation and prospect of comprehensive utilization of phosphogypsum[J].Inorganic Chemicals Industry,2024,56(1):1-8.
[40] POTGIETER J,POTGIETER S,MCCRINDLE R,et al. An investigation into the effect of various chemical and physical treatments of a South African phosphogypsum to render it suitable as a set retarder for cement[J]. Cement and Concrete Research,2003,33(8):1223-1227.
[41] LI B X,LI L,CHEN X,et al. Modification of phosphogypsum using circulating fluidized bed fly ash and carbide slag for use as cement retarder[J]. Construction and Building Materials,2022,338:127630.
[42] ERGEN?D,FORT R,VARAS-MURIEL M J,et al. Mortars and plasters—How to characterize aerial mortars and plasters[J].Archaeological and Anthropological Sciences,2021,13(11):1-28.
[43] VIJAYAN D S,MOHAN A,REVATHY J,et al. Evaluation of the impact of thermal performance on various building bricks and blocks:A review[J]. Environmental Technology&Innovation,2021,23:101577.
[44]汤银浩.工业副产石膏(磷石膏)作为缓凝剂在水泥中的应用[J].江苏建材,2021(4):37-39.TANG Y H. The application of industrial by-product gypsum(phosphogypsum)as a retarder in cement[J]. Jiangsu Building Materials,2021(4):37-39.
[45]杨永,王如峰,杨振.石膏基防火门芯板生产技术[J].建材发展导向,2019,17(20):68-69.YANG Y,WANG R F,YANG Z. Production technology of gypsum-based fireproof door core panel[J]. Development Guide to Building Materials,2019,17(20):68-69.
[46] GONG X Q,LIU J S,SUN Z G,et al. Effects of phosphogypsum and calcined phosphogypsum content on the basic physical and mechanical properties of Portland cement mortar[J]. Journal of Testing and Evaluation,2020,48(5):20180380.
[47]赵晨阳,吴丰辉,瞿广飞,等.废石膏制备硫酸钙晶须的高附加值利用前景[J].环境化学,2022,41(3):1086-1096.ZHAO C Y,WU F H,QU G F,et al. The high value-added utilization prospect of calcium sulfate whiskers prepared from waste gypsum[J]. Environmental Chemistry,2022,41(3):1086-1096.
[48] ZDAH I,AZIFA A,ENNACIRI Y,et al. Green method of phosphogypsum waste conversion to lithium sulfate monohydrate and calcium hydroxide[J]. Sustainable Chemistry and Pharmacy,2022,30:100850.
[49]郑河,吴俊虎,李珊,等.我国磷石膏全量治理策略与技术途径[J].磷肥与复肥,2024,39(1):27-31.ZHENG H, WU J H, LI S, et al. Strategy and technical approach for total treatment of phosphogypsum in China[J].Phosphate&Compound Fertilizer,2024,39(1):27-31.
[50]徐长忠,於金浩,李义连.磷石膏的预处理和综合利用研究进展[J].安全与环境工程,2024,31(1):260-270.XU C Z,YU J H,LI Y L. Research progress of pretreatment and comprehensive utilization of phosphogypsum[J]. Safety and Environmental Engineering,2024,31(1):260-270.
[51] GORBOVSKIY K G,RYASHKO A I,KAZAKOV A I,et al. The influence of water-soluble impurities on thermal dehydration kinetics of phosphogypsum in self-generated atmosphere[J].Journal of Thermal Analysis and Calorimetry,2018,133(3):1549-1562.
[52] MELGA?O L A O,QUITES N C,LE?O V A. Phosphogypsum as sulfate source for sulphate-reducing bacteria in a continuous fluidized-bed reactor[J]. Engenharia Sanitaria e Ambiental,2020,25:157-165.
[53] SAGNA Y P,DIEDHIOU S,GOUDIABY A O K,et al. Do phosphogypsum combined with organic amendments improve rice growth in a saline environment?[J]. Current Journal of Applied Science and Technology,2023,42(35):52-61.
基本信息:
DOI:
中图分类号:TQ177.375
引用信息:
[1]张瞿天,梁处芳,阮耀阳等.磷石膏无害化与资源化研究现状[J].生态产业科学与磷氟工程,2025,40(01):84-90.
基金信息:
湖北省技术创新计划项目重点研发专项公益事业类项目(2023BCB114); 湖北三峡实验室创新基金(SC211013)