| 14 | 0 | 23 |
| 下载次数 | 被引频次 | 阅读次数 |
磷化氢在工业上用于生产半导体器件和集成电路，也用于有机合成。磷化氢性质特殊，其火灾危险性为甲类，属于易燃气体类别1；磷化氢属于危险化学品、剧毒化学品和高毒化学品，职业性接触毒物危害程度为极度危害（Ⅰ级），急性毒性-吸入类别2。以某电子级磷化氢项目为例，设计考虑判定项目中人员集中建筑，结合定量风险分析的结果，说明在设计过程中需要考虑防火、防爆和防毒等相关措施，以及对应的工程防护对策。
Abstract：Phosphine is used in industry for the production of semiconductor devices and integrated circuits, and is also used in organic synthesis. Phosphine has special properties, and its fire risk is Class A, belonging to the flammable gas class 1; Phosphine belongs to dangerous chemicals, highly toxic chemicals and highly toxic chemicals, the degree of occupational exposure to poisons is extremely harmful(Class I), acute toxicity-inhalation category 2. Taking an electronic grade phosphine project as an example, the design consideration determines the construction of personnel concentration in the project, and combined with the results of quantitative risk analysis, it shows that the relevant measures such as fire prevention, explosion prevention and antivirus should be considered in the design process, as well as the corresponding engineering protection countermeasures.
[1]韩新宇，韩长秀，毕成良，等.磷化氢尾气制备超纯磷生产工艺的风险评价[J].安全与环境学报，2008,8(4):160-163.HAN X Y,HAN C X,BI C L,et al. Improved risk assessment method in producing ultra-pure phosphorus by using phosphine vented from the industry[J]. Journal of Safety and Environment,2008,8(4):160-163.
[2]杨长醋，张泽生，张莉.磷化氢气柜泄露和爆炸环境风险分析[J]天津化工，2010,24(3):42-44.YANG C C,ZHANG Z S,ZHANG L. Environmental risk analysis on the explosion of phosphine gas tank leak[J]. Tianjin Chemical Industry,2010,24(3):42-44.
[3]刘亚朝，李少鹏，赵洪祥.计算流体力学模拟高压储氢设施泄漏后果[J].厦门大学学报（自然科学版），2023,62(1):103-110.LIU Y Z,LI S P,ZHAO H X. Computational fluid dynamics simulation of leakage consequences of high pressure hydrogen storage facilities[J]. Journal of Xiamen University(Natural Science),2023,62(1):103-110.
[4]李冬.H2S制硫酸装置外部安全防护距离设计[J].云南化工，2019,46(4):108-112.LI D. Design of external Safety Protection distance for an Acid Gas sulfuric Acid Plant[J]. Yunnan Chemical Technology,2019,46(4):108-112.
[5]范咏峰，李少鹏，韦建树.控制室面向有爆炸风险侧是否可以有门窗浅析[J].流程工业，2022(6):33-37.FAN Y F,LI S P,WEI J S. Analysis on whether there can be doors and windows facing the side with explosion risk in the control room[J]. Process Industry,2022(6):33-37.
[6]李冬，陶刚，张礼敬，等.尿素合成塔内化学爆炸机理分析[J].安全与环境学报，2011,11(2):191-195.LI D,TAO G,ZHANG L J,et al. Theoretical analysis on the urea reactor explosion accidents[J]. Journal of Safety and Environment,2011,11(2):191-195.
[7]刘涛涛，贾泉升，刘成.多组分可燃气体爆炸极限研究现状及探讨[J].工业安全与环保，2022,48(9):53-55.LIU T T,JIA Q S,LIU C. Research status and discussion on explosion limit of multi-component combustible gas[J]. Industrial Safety and Environmental Protection,2022,48(9):53-55.
[8]张佳丽，林佳曼，强火生，等.磷化氢中毒症状、急救及毒理学研究进展[J].复旦学报（医学版），2023,50(5):771-779.ZHANG J L,LIN J M,QIANG H S,et al. Research progress on symptoms,first aid and toxicology of phosphine poisoning[J].Fudan Univ J Med Sci,2023,50(5):771-779.
[9]章志洋，张学锋，杨武洲，等.化工厂复杂火灾环境中的热辐射区域仿真研究[J/OL].重庆工商大学学报（自然科学版）.https://link.cnki.net/urlid/50.//55.N.20240910.1138.002ZHANG Z Y,ZHANG X F,YANG W Z,et al. Simulation Study of Thermal Radiation Zones in Complex Fire Environments in Chemical Plants[J/OL]. Journal of Chongqing Technology and Business University(Natural Science Edition).https://link.cnki.net/urlid/50.//55.N.20240910.1138.002
[10]李冬.某酸性气制硫酸装置防爆防毒避难设计总结[J].硫磷设计与粉体工程，2023(4):36-40,46.LI D. Summary of Explosion-proof and Toxic-proof Evacuation Design of an Acid Gas Sulfuric Acid Plant[J]. S P&BMH Related Engineering,2023(4):36-40,46.
基本信息:
DOI：
中图分类号:TQ086;TQ126.33
引用信息:
[1]李冬.某磷化氢项目安全设计[J].生态产业科学与磷氟工程,2025,40(05):118-123.
基金信息: